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Updated: Aug 5, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Published on: April 19, 2019

Mesoionic ligands and systems beyond singlet carbenes

Rajendra S Ghadwal1

  • 1Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, D-33615, Bielefeld, Germany. rghadwal@uni-bielefeld.de.

Chemical Society Reviews
|July 30, 2026
PubMed
Summary

Mesoionic carbenes (MICs), including imidazole-based (iMICs) and triazole-based (tMICs), are versatile ligands. New functionalized MICs with diverse donor atoms expand possibilities in organometallic chemistry, catalysis, and materials science.

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