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Modulation of ultrathin mesoporous porphyrin MOF nanosheets with ZnILs for highly efficient ambient CO2 conversion
Yajuan Li1, Boyu Xiao1, Yushan Zhang1
1Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, PR China. xiaoyi@hunnu.edu.cn.
Abstract:
A series of ultrathin (~1.50-1.77 nm) mesoporous MOF (mMOF, mesopore of 7.5-46 nm) nanosheets, 2D mM-TCPP (M = Mg2+, Ca2+, or Sr2+), were fabricated via a dual-structure-directing-agent (DSDA) approach by utilizing PVP/1,3,5-trimethylbenzene co-templates. Stable 2D C12[mim]2ZnBr4@mMg-TCPP formed using multifunctional metal ionic liquid (MIL) guests gave 95% yield for styrene carbonate under cocatalyst, solvent-free and ambient conditions, showing remarkable overall reusability.
