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Published on: July 31, 2016
Interface-orchestrated charge migration in Cu-MOF-74/Bi2S3 heterostructures for highly selective CO2 photoreduction
Jing-Shan Fan1, Xiang-Yu Lu1, Zhao-Feng Qiu1
1Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Centre of Advanced Microstructures, Nanjing University, Nanjing 210023, China. sunwy@nju.edu.cn.
Abstract:
Electrostatically assembled Cu-MOF-74/Bi2S3 (CB) heterostructures were found to enable efficient CO2 photoreduction by promoting interfacial charge migration and *COOH intermediate formation. The optimized heterostructure achieves 27.5-fold enhanced CO production compared with pristine Cu-MOF-74.
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