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Updated: Aug 13, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Dihydrogen pnictogenides of the alkaline earth metals beryllium, magnesium and calcium
Nick Michel1, Chantsalmaa Berthold1, Hanne Schmücker1
1Fachbereich Chemie and mar.quest│Marburg Center for Quanten Materials and Sustainable Technology, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043 Marburg, Germany. haenisch@chemie.uni-marburg.de.
Abstract:
Alkaline earth metal dihydrogen pnictogenides were obtained by deprotonation of PnH3 (Pn = P, As) with M(hmds)2 (M = Mg, Ca, Pn = P, As, hmds = hexamethyldisilazanide) in pyridine as the solvent. The beryllium compounds [Be(tmeda)(PH2)2] (tmeda = N,N,N',N'-tetramethylethylene diamine) and [Be(tmeda)(AsH2)2] were accessible via salt metathesis reactions between BeCl2 and [Li(tmeda)PnH2]. The products were examined by means of NMR and IR spectroscopy as well as X-ray diffraction experiments.
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