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Photochemistry of the Hydrogen Selenide-Sulfur Dioxide Complex: Formation of Selenosulfurous Acid and the

Mengqi Luan1, Junjie Jiang1, Tarek Trabelsi2

  • 1Department of Chemistry, Advanced Institute of Future Energy, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials For Separation and Conversion, Fudan University, Shanghai, China.

Angewandte Chemie (International Ed. in English)
|August 12, 2026
PubMed

Keywords:
chalcogen Bondscharge‐transfermatrix isolationphotoisomerizationpolyinterchalcogen compounds

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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