Related Experiment Video

Updated: Aug 14, 2026

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−
06:53

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−

Published on: July 27, 2018

Vibrational Autodetachment and Valence-to-Nonvalence Population Transfer in the Nitromethane Anion

Sejun An1, Dabin Kim1, Sang Kyu Kim1

  • 1Department of Chemistry, KAIST, Daejeon34141, Republic of Korea.

The Journal of Physical Chemistry Letters
|August 13, 2026
PubMed
Summary

Vibrational Feshbach resonances in nitromethane anions are explored using time-resolved photoelectron spectroscopy. Autodetachment is limited by intramolecular vibrational redistribution, revealing new dynamics in electron-driven chemistry.

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