Orientational bistability and field-controlled switching of a superparamagnetic dimer

We study the orientational dynamics of superparamagnetic colloidal dimers that carry both an induced magnetic moment, proportional to the applied field, and an effective permanent moment. In a static, uniform magnetic field, dimers that are permanently fixed together hop between two preferred in-plane angles, developing a bimodal steady-state orientation distribution. When the same field is periodically reversed, we observe a sharp, field-controlled change in the dynamical response from small hopping events with Δθ ≪ π to full Δθ ≈ π rotations on each field flip. We show that both the static bistability and the switching bifurcation can be rationalised by a magnetic response in the dimer that consists of both a strong induced and weak body-fixed component. This leads to a complex orientational energy landscape, with coupled roll-yaw rotations of the dimer responsible for the bistable dynamics. By combining the misorientation between dimer axis and field, bifurcation field strength and short-time orientational variance, we determine the magnitude and orientation of the net permanent dipole, thereby characterising details of the internal magnetic structure of the particles via microscopy.