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Supercritical transition of Yukawa fluids identified by excess entropy
1Soochow University, Institute of Plasma Physics and Technology, Jiangsu Key Laboratory of Frontier Material Physics and Devices, School of Physical Science and Technology, Suzhou 215006, China.
Abstract:
Equilibrium molecular dynamical simulations of three-dimensional (3D) Yukawa fluids are performed to investigate thermodynamics and supercritical transition of 3D dusty plasma fluids. The normalized reduced excess entropy s_{ex}/s_{ex}^{m} of 3D Yukawa fluids (where s_{ex}^{m} is the excess entropy at the melting point) is calculated from their reduced excess internal energy u_{ex}, so that different variation trends of s_{ex}/s_{ex}^{m}∝Γ^{0.5} and ∝Γ^{2} are obtained at lower and higher temperatures, respectively. A fitting expression for s_{ex}/s_{ex}^{m} of 3D Yukawa fluids for all temperatures is proposed here, leading to the general expression of the excess internal energy. The relative deviation of s_{ex}/s_{ex}^{m} with respect to the power law scaling is introduced as Δ, so that the criterion of Δ=10% is proposed to determine the supercritical transition of 3D Yukawa fluids between the liquidlike and gaslike states. It is found that the supercritical transition points of 3D Yukawa fluids identified from Δ=10% well agree with the previous results from other criteria.
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