Compositionally Tunable Interpolymer System for Charge-Selective Recovery of Gold Cyanide from Ferrocyanide-Rich...

Selective recovery of gold from cyanide leach liquors is hindered by the co-dissolution of iron minerals that generate ferrocyanide complexes which strongly compete with [Au(CN)₂]^- at ion-exchange sorbents. Here, we investigate mixed-bed interpolymer systems (IPS) composed of a strong-acid sulfonated polystyrene-divinylbenzene cation exchanger (TC007, Na⁺ form) and a strong-base quaternary ammonium anion exchanger (AV-17-8, Cl^- form) as a charge-selective platform for gold cyanide recovery. IPS compositions spanning cation-to-anion molar ratios from 6:0 to 0:6 were evaluated in batch contact with binary model solutions containing 30 mg L^-1 each of [Au(CN)₂]^- and [Fe(CN)₆]^4- at pH 10 and 25 °C. The optimal 1:5 IPS achieved an [Au(CN)₂]^- extraction degree of 79.88% and a selectivity coefficient β = D_Au/D_Fe = 4.95 at 48 h, whereas the pure AV-17-8 anion exchanger (0:6) reached only 37.55% Au extraction at 48 h, following an atypical delayed-uptake kinetic profile rather than the rapid, near-quantitative capture expected of an unmodified strong-base resin. Sorption kinetics were best described by a pseudo-second-order model (R² = 0.9992), confirming ion exchange at quaternary ammonium sites as the dominant rate-controlling step, with a ~30-fold increase in k₂ for [Au(CN)₂]^- in the 1:5 IPS relative to AV-17-8 alone. FTIR spectroscopy and TGA-DSC revealed the incorporation of metal cyanide complexes into the IPS matrix, with diagnostic C≡N stretching bands at 2108.7 and 2034.1 cm^-1 and an additional thermal event at 200-280 °C. These findings establish compositionally tunable IPS based on commercially available resins as a charge-selective sorbent platform demonstrating a capacity to regenerate under single-cycle elution conditions for gold cyanide recovery from ferrocyanide-containing process streams while highlighting the need for further evaluation under industrial Fe:Au ratios.