Related Experiment Video
Updated: Sep 23, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
Published on: June 8, 2018
Eigenstate condensation in quantum systems with finite-dimensional Hilbert spaces
Christopher David White1, Michael Winer2,3, Noam Bernstein1
1U. S. Naval Research Laboratory, Center for Materials Physics and Technology, Washington DC 20375, USA.
Abstract:
Random quantum states drawn from the Haar ensemble with a constraint on the energy expectation value E_{av}=〈ψ|H|ψ〉 display eigenstate condensation: For E_{av} below a critical value E_{c-} or above E_{c+}, they develop macroscopic overlap with the ground state or anti-ground state. We use analytical calculations and state-of-the-art numerical methods to investigate the eigenstate condensation phase transition. We give compact expressions for the critical energies, derive an analytical scaling form for the order parameter in systems with an extensive free energy, show that in those systems the phase transition itself has exponential rather than power-law finite-size scaling, and test these results with large-scale numerical sampling in random matrices and a range of local spin Hamiltonians. In local spin systems the two critical energies approach the middle of the spectrum as 1/V with V the number of spins. Our scaling form, however, demonstrates that the condensation phase transitions have exponential, rather than polynomial, finite-size scaling, which justifies treating the high-temperature phase as an extended phase.
Related Concept Videos
The Quantum-Mechanical Model of an Atom
Atomic Nuclei: Nuclear Spin State Overview
Phase Transitions: Vaporization and Condensation
2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...
The Entropy as a State Function
