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Updated: Sep 25, 2026

Interfacial Molecular-level Structures of Polymers and Biomacromolecules Revealed via Sum Frequency Generation Vibrational Spectroscopy
Published on: August 13, 2019
Wave-selected centrifugal fingering at a locally miscible interface
Luigi Davide Gala1, Daniele Tammaro1, Gerald G Fuller2
1Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università degli Studi di Napoli "Federico II", P. le Tecchio, 80, Naples, 80125, Italy.
Hypothesis:
Interfaces between locally miscible fluids subjected to oscillatory shear are expected to destabilize through a mechanism analogous to Kelvin-Helmholtz instability, and we hypothesize that centrifugal forcing under rotational oscillation can subsequently amplify this wave state into radial fingers, coupling two distinct instability mechanisms within a single interfacial system.
Experiments:
We studied a stratified system of polydimethylsiloxane and acetone in a cylindrical vessel under sinusoidal rotational forcing at frequencies of 5 to 20 Hz, using top-view and side-view imaging to track interfacial wave onset, wavelength selection, and subsequent radial finger growth, complemented by pendant-drop tensiometry to quantify the effective interfacial tension of the locally miscible pair.
Findings:
Oscillatory shear first organizes the interface into an azimuthally periodic wave state whose onset and wavelength match oscillatory Kelvin-Helmholtz theory once viscous stresses are included; centrifugal forcing then selectively amplifies wave crests into fingers, a process governed by a local radial mobility parameter contrasting centrifugal and viscous pressure drops, and all post-onset growth data collapse under a single centrifugal-viscous timescale, ruling out classical Saffman-Taylor, Faraday, and Rayleigh-Taylor mechanisms as the origin of the pattern.
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