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Updated: Sep 26, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
The Reactivity of Haloalkanes on Superatomic Niobium Clusters: Demethylation versus Dehydrogenation
Demiao Ma1,2, Xin Lei1, Jianglu Yuan1,2
1Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China.
Abstract:
The catalytic cleavage of C-H and C-X (X = Cl, Br, I) bonds in alkanes and their halides over transition metals has drawn considerable attention due to the broad applicability in synthesizing commodity and fine chemicals. However, the dynamic reaction mechanisms of halomethanes on nanometals are still not fully understood. In this study, we report a comprehensive study into the gas-phase reactivity of niobium clusters Nbn - (n = 5-50) with haloalkanes CH3X (X = Cl, Br, I). These anionic clusters react vigorously with haloalkanes via an efficient demethylation pathway, yielding predominantly niobium-halide products NbnXm -, and the reactions of CH3I allow for both demethylation and dehydrogenation. Thermodynamic and kinetic analyses elucidate the reaction mechanisms and clarify how halogen substituents influence cluster-mediated reactivity. This work provides a solid foundation for the rational design of niobium-based catalysts constructed from superatom frameworks.
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