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Published on: December 4, 2017
Microscopic Theory of a Fluctuation-Induced Dynamical Crossover in Supercooled Liquids
Corentin C L Laudicina1, Liesbeth M C Janssen1,2, Grzegorz Szamel3
1Eindhoven University of Technology, Soft Matter and Biological Physics, Department of Applied Physics, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Abstract:
Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing discrepancy by incorporating critical dynamical fluctuations into a microscopic mode-coupling framework. We show that these fluctuations round off the mean-field singularity and restore ergodicity at all finite densities (or temperatures) without invoking activated dynamics or facilitation. The resulting effective theory describes the order parameter as a stochastic process with self-induced, annealed disorder, determined self-consistently at the mean-field level. In the β-relaxation regime it reduces to stochastic beta-relaxation theory, thereby unifying mode-coupling and replica-based approaches beyond mean field. All parameters of the stochastic beta-relaxation theory are fixed by the static structure, enabling parameter-free predictions that extend mean-field theory into finite dimensions.
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