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Medium-sized [(η2-P15)Mo(CO)4]3-: an unsymmetrically mono-inserted polyphosphorus scaffold
Minghao Deng1, Qiang Wang2, Yuan Shui2
1Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China. panfx@lzu.edu.cn,shaoylc@lzu.edu.cn.
Abstract:
The (formal) replacement of one P atom of P162- by {Mo(CO)4} resulted in the isolation of [(η2-P15)Mo(CO)4]3- (1) as its [Na(crypt-222)]+ salt. Quantum-chemical calculations show that anion 1 preserves the overall P162--derived framework, but undergoes local geometric opening and electronic redistribution at the insertion site.
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