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Published on: July 25, 2025
Targeted engineering of heteronuclear bimetallic atomic sites on covalent triazine frameworks toward CO2
Liying Fang1, Peng Zhou1, Zhiwen Zhao2
1Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao, 266237, China. liuxj2020@sdu.edu.cn.
Abstract:
Rational design of heteronuclear bimetallic atomic sites anchored on covalent triazine frameworks (CTFs) for synergistic CO2 photoreduction lacks guiding principles. We identify CoRe@CTF, NiRe@CTF, and ZnRe@CTF with weak Coulomb attraction and a large electron-hole centroid distance for charge separation, offering a roadmap for targeted engineering of heterodiatomic CTF-based CO2 photocatalysis.
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