Anthropogenic tritium as a continental-scale tracer in river-derived recharge

Groundwater, enhanced through managed aquifer recharge (MAR), plays a central role in mitigating current and future water stress. Here we evaluate anthropogenic and natural water isotopes as tracers of groundwater flow dynamics within alluvial MAR systems. High-resolution sampling (daily/weekly) of stable isotopes (δ¹⁸O and δ²H) and tritium (³H), influenced by nuclear power plant effluents, is used to trace and quantify the movement of infiltrated river water through an alluvial aquifer along the Rhine River in Switzerland. Time-series deconvolution is applied to quantify the tracer-based travel time distribution and to predict travel times throughout the entire MAR scheme. The results demonstrate the suitability of ³H as a quasi-conservative travel time tracer in systems where the infiltrating river water is marked by nuclear power plant discharges-a situation prevalent along the banks of many large river basins globally. Deuterium excess proved equally effective as a bulk travel time tracer, reflecting distinct seasonal meltwater signals expected in major European rivers. These findings quantify MAR recovery rates and wellhead protection zones, supporting sustainable groundwater management under natural and anthropogenic pressures.