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Visible-light-induced perfluoroalkylation of sulfenamides via ternary EDA complexes
Zhihao Yu1, Daijun Tang1, Jinfeng Liu1
1College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, P. R. China. xjiang@zjut.edu.cn.
Chemical Communications (Cambridge, England)
|October 12, 2026
Abstract:
Herein, we report a copper-assisted visible-light-induced perfluoroalkylation of sulfenamides via a ternary electron donor-acceptor complex, enabling rapid and highly S-selective synthesis of perfluoroalkyl sulfilimines from structurally diverse sulfenamides under mild conditions.