A water-soluble 'turn-on' fluorometric sensor for Zn2+ and Cd2+ detection, quantification, and discrimination in
Yelyzaveta V Antsybora1, Cordelia Y Adams1, Amelia Golus2
1Ontario Tech University (University of Ontario Institute of Technology), 2000 Simcoe Street North, Oshawa, ON L1G 0C5, Canada. olena.zenkina@ontariotechu.ca.
Abstract:
A 4'-hydrazineyl-2,2':6',2″-terpyridine-based fluorescent probe achieves "turn-on" detection of Zn2+ and Cd2+ in water at picomolar concentrations, far below regulatory limits. Combined experimental and computational studies reveal the nature of the metal complexes, while successful analysis of Lake Ontario freshwater samples and paper-based test strips demonstrate its potential for practical environmental monitoring.
Related Concept Videos
Photoluminescence: Applications
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
Fluorescence and Phosphorescence: Instrumentation
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.


