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![Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F55858.jpg&w=3840&q=50)
Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
Published on: December 4, 2017
Bioinspired proton relay on amino-functionalized PdCe metallene accelerates hydrogen oxidation kinetics and CO
Tianheng Du1, Xueheng Liu1, Tao Song1
1School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China. zhouxi@ntu.edu.cn.
Abstract:
Inspired by [FeFe]-hydrogenases, a polyaniline-functionalized PdCe metallene mimics the enzyme's secondary coordination sphere, achieving triple synergy that weakens H* binding, relays protons via -NH- groups, and shields against CO. The catalyst surpasses Pt/C in HOR kinetics with only 1.2% activity loss under 100 ppm CO, establishing secondary-sphere engineering as a paradigm for CO-immune Pt-free HOR catalysts.
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