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Stereoselective Gateway to Decorated Chloro-1,3-butadienes from Allenols via Deoxygenative 1,2-Bond Migration
1Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab140001, India.
Abstract:
We disclose an efficient strategy for the selective synthesis of E-2-chloro-1,3-butadienes from allenols. This modular approach offers an extensive substrate scope with moderate-to-good yields and operational simplicity. Additionally, they offer a versatile platform for synthetic diversification and are highly scalable.
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