Ligand Symmetry Modulates Singlet-Triplet Energy Gap for Tunable Luminescence Temperature Sensing Performance
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Published on: September 16, 2014
Jun-Reng Wu1, Jun-Yi Wu1, Zong-Ren Chen1
1Jiangmen Key Laboratory of Synthetic Chemistry and Cleaner Production, School of Environmental and Chemical Engineering, Wuyi University, Jiangmen, Guangdong529000, China.
Abstract:
The influence of reverse intersystem crossing on temperature response is a highly intriguing research topic for TADF materials. In this work, we report three isostructural Cu(I) coordination polymers featuring ligands with different symmetries. We tailor their singlet-triplet energy gap to systematically investigate its impact on temperature-responsive properties.
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