An [Fe32] molecular metal oxide
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Updated: Nov 10, 2026

Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats
Published on: June 13, 2018
Annabel J MacGregor1, Gary S Nichol1, Euan K Brechin1
1EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh EH9 3JF, Scotland, UK. ebrechin@ed.ac.uk.
Abstract:
Reaction of [Fe16] with 3-chloropyridine results in the formation of an [Fe32] cluster, whose magnetic skeleton describes interwoven triangular and square tiling. Magnetic measurements reveal competing antiferromagnetic exchange interactions, resulting in significant spin frustration.
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