Activating Hidden Magnons With Anomalous Rotational Symmetry

Correlated materials with competing spin-orbit and crystal-field interactions can host composite spin-orbital magnons that are highly susceptible to structural and electronic perturbations, enabling the control of magnetic dynamics beyond spin-only physics. Using Raman spectroscopy on ${\mathrm{Ca}}_2$ ${\mathrm{RuO}}_4$ , we show that the partial substitution of Ru with Mn reconstructs the magnon spectrum and reveals one-magnon modes that are hidden in the undoped state. We demonstrate that the transition-metal substitution activates otherwise symmetry-forbidden magnon modes through mirror-symmetry breaking of the underlying spin-orbital configuration. This effect can be theoretically explained by the local structural distortions induced in the ${\mathrm{RuO}}_6$ octahedra near the dopant, which enable the observation of mixed-parity one-magnon modes. These excitations display a distinctive polarization dependence, with a lowering from fourfold to twofold rotational symmetry arising from the mixed-parity character of the coupled magnons and interference between resonant and nonresonant scattering channels. Our results show that spin-orbit-lattice entanglement provides a route to tailoring collective magnetic excitations and their polarization response in spin-orbit-coupled correlated systems.