A total synthesis of ( )-fumagillin

Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on (S,S)-1,2-Diaminocyclohexane.

Organic letters·2026

Enantioselective Catalytic Oxidation of Olefins and Organosulfur Compounds by Chiral Mn(II) Diamino-Dicarboxylato or Disulfonato Complexes via a Pentacoordinate Mn(V)-Oxo Cation.

Organic letters·2026

Experimental Support for a Chiral Pentacoordinate, Axially Symmetric Cationic Mn(V)-Oxo Complex as the Key Reactant in the Highly Enantioselective Catalytic Epoxidation of Olefins.

Organic letters·2026

Highly Position- and Enantioselective Catalytic Epoxidation of Polyolefins Mediated by a Chiral Mn Complex, Including a One-Step Conversion of Squalene to the (S)-2,3-Epoxide, a Precursor of Natural Steroids and Terpenoids.

Journal of the American Chemical Society·2025

Synthetically Useful Transformations of Olefins via Cationic 1,2-Oxazetium Intermediates.

Organic letters·2023

Synthesis of Tetracyclic C2-Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation.

Organic letters·2023

A Complementary Approach to Dialkylsilylenes via Thermodynamically Stable Boron-Ate Silylenoids Derived from Chlorosilylboranes.

Journal of the American Chemical Society·2026

Geminal Difunctionalizations of Aliphatic Ketones and Aldehydes Enabled by Thioacetal Activation and Deep Electroreduction.

Journal of the American Chemical Society·2026

Direct Comparison of CuB and CuSiR Sites in a Single Designed Protein Scaffold Reveals a Central Role for Tyrosine in Oxygen and Sulfite Reduction.

Journal of the American Chemical Society·2026

Programmable Vacancy Topology in High-Entropy-Alloy-Inspired Multiprincipal Alloys Directs Ru-Centered Alkaline Hydrogen Evolution.

Journal of the American Chemical Society·2026

Achieving Organocatalytic Control of P(III)-Centered Chirality for the Construction of P(III)/(V) Stereogenic Compounds.

Journal of the American Chemical Society·2026

Electrochemical Cross-Coupling of Electron-Deficient Olefins.

Journal of the American Chemical Society·2026

Rhodium-catalyzed regio- and stereoselective β-C(sp2)-H amidation of enamines with dioxazolones to access vicinal diamines.

Chemical communications (Cambridge, England)·2026

Photocatalyst-free visible light mediated cascade sulfonylation/annulation of N-propargyl arylsulfonamides: accessing E- and Z-4-sulfonylmethylidene benzosultams.

Chemical communications (Cambridge, England)·2026

Recent advances in cyclization reactions of conjugated ynals.

Chemical communications (Cambridge, England)·2026

Highly Chiral MoS2 Flakes With Redox-Active Centers for Spin Selective Water Oxidation.

Small science·2026

Cavity-arbitrated enantioinduction by calix[4]arene-annexed BINOL catalysts for cyanosilylation of aldehydes.

Chemical communications (Cambridge, England)·2026

C-S bond formation through nucleophilic substitution reaction of thiol derivatives with activated aryl halides.

iScience·2026

Related Experiment Videos

A total synthesis of ( )-fumagillin

Related Concept Videos

Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on (S,S)-1,2-Diaminocyclohexane.

Enantioselective Catalytic Oxidation of Olefins and Organosulfur Compounds by Chiral Mn(II) Diamino-Dicarboxylato or Disulfonato Complexes via a Pentacoordinate Mn(V)-Oxo Cation.

Experimental Support for a Chiral Pentacoordinate, Axially Symmetric Cationic Mn(V)-Oxo Complex as the Key Reactant in the Highly Enantioselective Catalytic Epoxidation of Olefins.

Highly Position- and Enantioselective Catalytic Epoxidation of Polyolefins Mediated by a Chiral Mn Complex, Including a One-Step Conversion of Squalene to the (S)-2,3-Epoxide, a Precursor of Natural Steroids and Terpenoids.

Synthetically Useful Transformations of Olefins via Cationic 1,2-Oxazetium Intermediates.

Synthesis of Tetracyclic C2-Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation.

A Complementary Approach to Dialkylsilylenes via Thermodynamically Stable Boron-Ate Silylenoids Derived from Chlorosilylboranes.

Geminal Difunctionalizations of Aliphatic Ketones and Aldehydes Enabled by Thioacetal Activation and Deep Electroreduction.

Direct Comparison of CuB and CuSiR Sites in a Single Designed Protein Scaffold Reveals a Central Role for Tyrosine in Oxygen and Sulfite Reduction.

Programmable Vacancy Topology in High-Entropy-Alloy-Inspired Multiprincipal Alloys Directs Ru-Centered Alkaline Hydrogen Evolution.

Achieving Organocatalytic Control of P(III)-Centered Chirality for the Construction of P(III)/(V) Stereogenic Compounds.

Electrochemical Cross-Coupling of Electron-Deficient Olefins.

Rhodium-catalyzed regio- and stereoselective β-C(sp2)-H amidation of enamines with dioxazolones to access vicinal diamines.

Photocatalyst-free visible light mediated cascade sulfonylation/annulation of N-propargyl arylsulfonamides: accessing E- and Z-4-sulfonylmethylidene benzosultams.

Recent advances in cyclization reactions of conjugated ynals.

Highly Chiral MoS2 Flakes With Redox-Active Centers for Spin Selective Water Oxidation.

Cavity-arbitrated enantioinduction by calix[4]arene-annexed BINOL catalysts for cyanosilylation of aldehydes.

C-S bond formation through nucleophilic substitution reaction of thiol derivatives with activated aryl halides.

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A total synthesis of ( )-fumagillin

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