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09:38
Biomembrane Fabrication by the Solvent-assisted Lipid Bilayer (SALB) Method
Published on: December 1, 2015
Diffusion of salts across a butanol-water interface
Biophysical Journal
|November 1, 1966
Abstract:
Diffusion of the chloride salts of Li, Na, K, Rb, and Cs from water into 1-butanol and from 1-butanol into water was examined at temperatures from 13-40 degrees C. Distribution coefficients, interfacial transfer coefficients, Arrhenius activation energy, free energy of activation, enthalpy, and entropy of activation were determined for the diffusion of these salts across the alcohol-water interface. The results indicate that the entropy decrease made the major contribution to the change in the free energy of activation.
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