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EXAFS: new horizons in structure determinations.

P Eisenberger, B M Kincaid

    Science (New York, N.Y.)
    |June 30, 1978
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    Extended X-ray Absorption Fine Structure (EXAFS) analysis, powered by synchrotron radiation, offers a potent method for determining material structures. This technique is advancing rapidly with new synchrotron sources, promising significant future developments in structural science.

    Area of Science:

    • Materials Science
    • Solid-State Physics
    • Chemistry

    Background:

    • Extended X-ray Absorption Fine Structure (EXAFS) phenomena observed since the 1930s.
    • EXAFS has evolved into a powerful structural determination technique with synchrotron radiation.

    Purpose of the Study:

    • To describe the theory and experimental practice of EXAFS.
    • To review diverse applications of EXAFS in various scientific fields.

    Main Methods:

    • Utilizing synchrotron radiation for EXAFS measurements.
    • Analysis of EXAFS data, exemplified with germanium.

    Main Results:

    • Demonstrated the utility of EXAFS for structural analysis.
    • Reviewed successful applications across diverse systems including biological molecules, catalysts, solutions, solids, and surfaces.

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    Conclusions:

    • EXAFS is a versatile and powerful structural probe.
    • Advancements in synchrotron sources will drive a revolution in structure determination.