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Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
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Nuclear overhauser studies of CCGGAp, ACCGGp, and ACCGGUp

M Petersheim, D H Turner

    Biochemistry
    |January 18, 1983
    PubMed

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    Nuclear Overhauser Enhancement (NOE)01:06

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    Irradiation of a spin-active nucleus causes an increase or decrease in the signal intensity of neighboring nuclei that are not necessarily chemically bonded or involved in J-coupling. This phenomenon, called the nuclear Overhauser enhancement (NOE), results from through-space interactions between the nuclear spins. The NOE effect decreases with increasing internuclear distance and is generally not observed beyond 4 angstroms. In NOE, dipole-dipole interactions between neighboring spin-active...