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Tyrosine phosphorylation of protein kinase C-delta in response to its activation

W Li1, H Mischak, J C Yu

  • 1Laboratory of Cellular and Molecular Biology, National Cancer Institute, Bethesda, Maryland 20892.

Insights

Protein kinase C delta (PKC-delta) undergoes tyrosine phosphorylation upon 12-O-tetradecanoylphorbol-13-acetate (TPA) stimulation. This phosphorylation enhances PKC-delta activity, suggesting a regulatory role in cellular signaling pathways.

Area of Science:

  • Cellular signaling
  • Molecular biology
  • Biochemistry

Background:

  • Protein kinase C (PKC) is a family of enzymes involved in various cellular processes.
  • Investigating the specific roles of different PKC isoenzymes is crucial for understanding cellular regulation.
  • Tyrosine phosphorylation is a key post-translational modification regulating protein function.

Purpose of the Study:

  • To investigate the signaling events regulated by protein kinase C (PKC) activation.
  • To determine if tyrosine phosphorylation of cellular proteins occurs following 12-O-tetradecanoylphorbol-13-acetate (TPA) treatment in cells expressing different PKC isoenzymes.
  • To identify the specific PKC isoenzyme, if any, that undergoes tyrosine phosphorylation.

Main Methods:

  • Retroviral vectors were used to express five different PKC isoenzymes (alpha, delta, epsilon, eta, zeta) in 32D hematopoietic cells and NIH-3T3 fibroblasts.
  • Cells were treated with 12-O-tetradecanoylphorbol-13-acetate (TPA) to activate PKC.
  • Tyrosine phosphorylation of cellular proteins was analyzed using Western blotting or similar techniques.
  • Purified PKC-delta was subjected to in vitro phosphorylation by src family or receptor tyrosine kinases.

Main Results:

  • TPA treatment induced pronounced, time-dependent tyrosine phosphorylation of an 82-kDa protein specifically in cells expressing PKC-delta.
  • The 82-kDa protein undergoing tyrosine phosphorylation was identified as PKC-delta itself.
  • Tyrosine phosphorylation of purified PKC-delta by src family or receptor tyrosine kinases in vitro enhanced its kinase activity.

Conclusions:

  • PKC-delta is a substrate for tyrosine phosphorylation in response to TPA stimulation.
  • Tyrosine phosphorylation of PKC-delta may serve as a positive regulatory mechanism, enhancing its enzymatic activity.
  • This finding reveals a novel regulatory mechanism for PKC-delta function in cellular signaling pathways.

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