Porphyrin-like compounds genesis under simulated abiotic conditions

Experiments with gas mixtures intended to simulate the primaeval atmosphere of the Earth yielded many biologically important chemicals. Investigations into the synthesis of porphyrin-like compounds from methane, ammonia and water vapour were carried out by using high frequency discharges. Microanalyses of porphyrins showed that porphyrin-like pigments were formed in this way. The presence of divalent cations in the reaction system increased the yield of porphyrin-like pigments also involving the direct synthesis of their metal complexes. The ready formation of these compounds in abiotic conditions is significant, suggesting the possibility of their appearance during the early stage of chemical evolution.