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Three new omega-cycloheptyl fatty acids from Alicyclobacillus cycloheptanicus and their biosynthetic
B S Moore1, H G Floss, K Poralla
1Department of Chemistry BG-10, University of Washington, Seattle 98195, USA.
Abstract:
Three minor omega-cycloheptyl fatty acids from Alicyclobacillus cycloheptanicus have been identified as omega-cycloheptylnonanoate, -decanoate, and -alpha-hydroxytridecanoate. The biosynthetic interrelations of these cyclic fatty acids have been studied. 13C-Labeled omega-cycloheptylundecanoate and -alpha-hydroxyundecanoate were converted to omega-cycloheptyldecanoate, which is one carbon shorter in length. alpha-Hydroxylation of omega-cycloheptylundecanate was also observed, but not chain extension to omega-cycloheptyltridecanoate.
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