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Nitric oxide-stimulated guanine nucleotide exchange on p21ras

H M Lander1, J S Ogiste, S F Pearce

  • 1Department of Pharmacology, Cornell University Medical College, New York, New York 10021, USA.

Insights

Nitric oxide (NO) directly activates the p21ras protein in human T cells by S-nitrosylation, mimicking guanine nucleotide exchange factors and enabling downstream signaling like NF-kappa B activation.

Area of Science:

  • Molecular Biology
  • Cell Signaling
  • Immunology

Background:

  • The protooncogene p21ras is a key mediator of extracellular signal transduction.
  • Understanding how p21ras is regulated is crucial for deciphering cellular responses.

Purpose of the Study:

  • To investigate the effect of nitric oxide (NO) on p21ras activation in human T cells.
  • To elucidate the mechanism by which NO activates p21ras.
  • To determine the role of p21ras in NO-induced downstream signaling.

Main Methods:

  • In vitro studies with purified recombinant p21ras.
  • Circular dichroism analysis to assess conformational changes.
  • Measurement of GTP-bound p21ras levels.
  • Assessment of NF-kappa B activation.

Main Results:

  • Nitric oxide (NO) directly and reversibly activates p21ras in human T cells, increasing GTP-bound p21ras.
  • NO induces a significant conformational change in p21ras, facilitating GDP/GTP exchange.
  • Activation occurs via S-nitrosylation of a critical cysteine residue on p21ras.
  • p21ras is essential for NO-mediated activation of downstream signaling pathways, including NF-kappa B.

Conclusions:

  • p21ras is a direct target of nitric oxide (NO) in T cells.
  • NO activates p21ras through S-nitrosylation, a mechanism similar to guanine nucleotide exchange factors.
  • This NO-induced p21ras activation is critical for downstream cellular responses in T cells.

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