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Application of one-dimensional nutation nuclear magnetic resonance to 51V in ferroelastic BiVO4
P P Man1, S H Choh, J Fraissard
1Laboratoire de Chimie des Surfaces, CNRS URA 1428, Université Pierre et Marie Curie, Paris, France.
Solid State Nuclear Magnetic Resonance
|August 1, 1994
Abstract:
The central line intensity of a spin I = 7/2, excited by a radio frequency (rf) pulse, is calculated by taking into account the first-order quadrupolar interaction during excitation. Thus, the result is valid for any ratio of quadrupolar coupling to pulse amplitude. The quadrupolar coupling of the nuclei vanadium 51V in a single crystal of ferroelastic BiVO4 is determined using this one-dimensional (1D) mutation method.