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Cationized Bowman-Birk protease inhibitor as a targeted cancer chemopreventive agent

H Ekrami1, A R Kennedy, H Witschi

  • 1Department of Pharmaceutical Sciences, John Stauffer Pharmaceutical Sciences Center, University of Southern California School of Pharmacy, Los Angeles 90033.

Insights

Spermine-conjugated Bowman-Birk inhibitor (BBI) shows promise as a lung-targeted cancer chemopreventive agent. Spermine-BBI is effective and less toxic than previous conjugates, suggesting improved therapeutic potential.

Area of Science:

  • Biochemistry
  • Pharmacology
  • Oncology

Background:

  • The Bowman-Birk inhibitor (BBI) conjugate with poly(D-lysine) (PDL-ss-BBI) was investigated as a lung-targeted anti-carcinogenic agent.
  • PDL-ss-BBI demonstrated dose-dependent reduction in lung tumors in mice but exhibited toxicity at higher doses.

Purpose of the Study:

  • To develop an improved lung-targeted anti-carcinogenic agent.
  • To synthesize and evaluate spermine-conjugated BBI (spermine-BBI) as a potential cancer chemopreventive agent.

Main Methods:

  • Spermine-BBI was synthesized by coupling BBI to spermine via amide bonds using carbodiimide chemistry.
  • In vitro transformation assays using C3H10T1/2 cells were performed to assess efficacy.
  • Biodistribution studies using [125I]spermine-BBI were conducted in mice.
  • In vitro cytotoxicity assays were performed on C3H10T1/2 cells.

Main Results:

  • Spermine-BBI exhibited comparable efficacy to BBI in reducing transformation yield in vitro.
  • Intravenous injection of [125I]spermine-BBI resulted in greater accumulation in the lungs and liver compared to BBI.
  • Spermine-BBI demonstrated 30-fold lower in vitro cytotoxicity than PDL-ss-BBI in C3H10T1/2 cells.

Conclusions:

  • Spermine-BBI represents a potentially improved lung-targeted cancer chemopreventive agent.
  • The reduced toxicity and favorable biodistribution profile suggest spermine-BBI could be a viable alternative to BBI and PDL-ss-BBI.

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