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Fast atom bombardment mass spectrometry of elymoclavine glycosides
V Havlícek1, M Flieger, V Kren
1Institute of Microbiology, Academy of Sciences of the Czech Republic, Prague.
Biological Mass Spectrometry
|February 1, 1994
Abstract:
A series of nine naturally occurring and/or semi-synthetic elymoclavine mono- and oligoglycosides containing various sugar units was investigated by fast atom bombardment, high-resolution measurements and linked scans. The fragmentations of the [M+H]+ and [M+Na]+ ions are described and their different contributions to the structure elucidation are discussed.