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Updated: Aug 17, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Conformational features of carrabiose polymers: I. Configurational statistics of kappa-carrageenan
R Urbani1, A Di Blas, A Cesàro
1Department of Biochemistry, Biophysics and Macromolecular Chemistry, University of Trieste, Italy.
Abstract:
Potential energy functions evaluating both repulsive-attractive van der Waals non-bonding interactions and electrostatic interactions have been used to evaluate the conformational energies of the repeating units of the kappa-carrageenan polymers. Structural parameters have been obtained by minimization MNDO procedures (MOPAC). Energy maps have been calculated for the (1-3) alpha-D-galactose-4-sulphate (GS) and the (1-4)-3,6-anhydro-alpha-D-galactose (A) residues, taking into account the conformational freedom of the sulphate group. The configurational statistics of the random coiled kappa-carrageenan chain have been explored, disclosing a highly flexible character, which can mainly be ascribed to the random occurrence of two different conformers of the GS-A dimeric unit.
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