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Related Concept Videos

Thermal Sigmatropic Reactions: Overview01:16

Thermal Sigmatropic Reactions: Overview

Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...
[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement01:21

[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
Preparation of 1° Amines: Hofmann and Curtius Rearrangement Overview01:07

Preparation of 1° Amines: Hofmann and Curtius Rearrangement Overview

In the presence of an aqueous base and a halogen, primary amides can lose the carbonyl (as carbon dioxide) and undergo rearrangement to form primary amines. This reaction, called the Hofmann rearrangement, can produce primary amines (aryl and alkyl) in high yields without contamination by secondary and tertiary amines.
Cycloaddition Reactions: MO Requirements for Thermal Activation01:16

Cycloaddition Reactions: MO Requirements for Thermal Activation

Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement01:24

[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement

The Claisen rearrangement is a [3,3] sigmatropic rearrangement of allyl vinyl ethers to unsaturated carbonyl compounds. The rearrangement is a concerted pericyclic reaction proceeding via a chair-like transition state.
Relative Motion Analysis using Rotating Axes-Problem Solving01:29

Relative Motion Analysis using Rotating Axes-Problem Solving

Consider a crane whose telescopic boom rotates with an angular velocity of 0.04 rad/s and angular acceleration of 0.02 rad/s2. Along with the rotation, the boom also extends linearly with a uniform speed of 5 m/s. The extension of the boom is measured at point D, which is measured with respect to the fixed point C on the other end of the boom. For the given instant, the distance between points C and D is 60 meters.
Here, in order to determine the magnitude of velocity and acceleration for point...

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Related Experiment Video

Updated: Jun 26, 2026

Establishment of a Clinic-based Biorepository
07:50

Establishment of a Clinic-based Biorepository

Published on: May 29, 2017

Arranging affiliation agreements and outside rotations

R L Willard1

  • 1West Virginia School of Osteopathic Medicine, Lewisburg.

The Journal of the American Osteopathic Association
|April 1, 1993
PubMed
Summary

Affiliation agreements are crucial for osteopathic medical education programs when training occurs at external sites. Reviewing key considerations ensures compliance and prevents future issues.

Area of Science:

  • Medical Education
  • Osteopathic Medicine
  • Healthcare Administration

Background:

  • Affiliation agreements are essential for sponsoring institutions that arrange educational components of internships or residencies at external hospitals.
  • These agreements are particularly relevant for colleges of osteopathic medicine and osteopathic hospitals serving as sponsoring institutions.

Purpose of the Study:

  • To outline fundamental considerations for establishing affiliation agreements in osteopathic medical education.
  • To highlight requirements set by the American Osteopathic Association and other factors necessary for smooth program execution.

Main Methods:

  • Review of essential elements for affiliation agreements.
  • Identification of negotiable factors and institutional acceptance criteria.

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  • Emphasis on the necessity of legal review for all agreements.

    • Main Results:

    • Key considerations for affiliation agreements have been identified.
    • Compliance with American Osteopathic Association requirements is addressed.
    • Strategies to prevent complications and ensure clarity in agreements are presented.

    Conclusions:

    • Careful review and agreement on key considerations are vital before finalizing affiliation agreements.
    • Formalizing these agreements with legal counsel is a critical step.
    • Well-structured affiliation agreements support the integrity of osteopathic internship and residency programs.