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Related Experiment Videos

Anthracene-1,8-dicarboxylic acid

L J Fitzgerald1, R E Gerkin

  • 1Department of Chemistry, Ohio State University, Columbus 43210, USA.

Acta Crystallographica. Section C, Crystal Structure Communications
|July 15, 1996
PubMed
Summary
This summary is machine-generated.

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This study details the crystal structure of anthracene-1,8-dicarboxylic acid, revealing ordered carboxyl groups and zigzag hydrogen-bonded chains. These chains form discrete structures with specific intermolecular interactions.

Area of Science:

  • Crystallography
  • Organic Chemistry
  • Materials Science

Background:

  • Anthracene derivatives are important in organic electronics and materials science.
  • Understanding the crystal packing and intermolecular interactions is crucial for predicting material properties.

Purpose of the Study:

  • To determine the crystal structure of anthracene-1,8-dicarboxylic acid.
  • To analyze the hydrogen bonding and molecular arrangement in the solid state.

Main Methods:

  • Single-crystal X-ray diffraction was used to elucidate the crystal structure.
  • Analysis of bond distances, angles, and intermolecular contacts was performed.

Main Results:

  • Anthracene-1,8-dicarboxylic acid crystallizes in the noncentrosymmetric space group P2(1)2(1)2(1).

Related Experiment Videos

  • Ordered carboxyl groups and near twofold symmetry of the anthracene core were observed.
  • Molecules form zigzag chains via cyclic-dimer hydrogen bonding, with discrete chains separated by van der Waals interactions.

    • Conclusions:

    • The crystal structure provides insights into the packing and intermolecular forces of anthracene-1,8-dicarboxylic acid.
    • The observed hydrogen bonding pattern influences the material's structural organization.
    • This detailed structural information is valuable for designing related functional materials.