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Expression, purification, and crystallization of meso-diaminopimelate dehydrogenase from Corynebacterium glutamicum
S G Reddy1, G Scapin, J S Blanchard
1Department of Biochemistry, Albert Einstein College of Medicine, Bronx, New York 10461, USA.
Abstract:
The gene encoding the meso-diaminopimelate dehydrogenase (DAPDH) from Corynebacterium glutamicum was over-expressed and purified to homogeneity. Crystals of the binary DAPDH-NADP+ complex were obtained from solutions of polyethylene glycol 8000, 100 mM sodium cacodylate, pH 6.5, and 150-300 mM Mg(OAc)2. The crystals diffract to 2.2 A, belong to the orthorhombic space group P2(1), and contain two molecules per asymmetric unit.
Insights
Crystallization of meso-diaminopimelate dehydrogenase (DAPDH) from Corynebacterium glutamicum in complex with NADP+ was achieved. This structural study provides insights into the enzyme
Area of Science:
- Biochemistry
- Structural Biology
- Crystallography
Background:
- Meso-diaminopimelate dehydrogenase (DAPDH) is a key enzyme in the biosynthesis of lysine in certain bacteria.
- Understanding the structure of DAPDH is crucial for developing potential antimicrobial agents targeting this pathway.
Purpose of the Study:
- To obtain high-quality crystals of the DAPDH-NADP+ complex for structural determination.
- To characterize the crystallographic properties of the DAPDH-NADP+ complex.
Main Methods:
- Over-expression and purification of Corynebacterium glutamicum DAPDH.
- Crystallization screening using polyethylene glycol 8000 and magnesium acetate.
- X-ray diffraction analysis of the obtained crystals.
Main Results:
- Homogeneous DAPDH enzyme was successfully purified.
- Crystals of the binary DAPDH-NADP+ complex were obtained.
- The crystals belong to the orthorhombic space group P2(1) and diffract to 2.2 Å resolution.
Conclusions:
- The successful crystallization of the DAPDH-NADP+ complex paves the way for detailed structural analysis.
- This structural information can aid in understanding enzyme mechanism and inhibitor design.