Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Spatially resolved solid-state MAS-NMR-spectroscopy

U Scheler1, G Schauss, B Blümich

  • 1Max-Planck Institut für Polymerforschung, Mainz, Germany.

Solid State Nuclear Magnetic Resonance
|July 1, 1996
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Investigation of the late-Roman burial chamber at Reichertsberg in Trier by NMR depth profiling.

Solid state nuclear magnetic resonance·2026
Same author

From LASER physics to the para-hydrogen pumped RASER.

Progress in nuclear magnetic resonance spectroscopy·2019
Same author

Polarization transfer efficiency in PHIP experiments.

Physical chemistry chemical physics : PCCP·2017
Same author

Mechanochemical route to the synthesis of nanostructured Aluminium nitride.

Scientific reports·2016
Same author

MRI and dental implantology: two which do not exclude each other.

Biomaterials·2015
Same author

Moisture dynamics in wall paintings monitored by single-sided NMR.

Magnetic resonance in chemistry : MRC·2014
Same journal

Experimental and computational <sup>11</sup>B NMR comparative study of MOVPE-grown rhombohedral and bulk hexagonal boron nitride.

Solid state nuclear magnetic resonance·2026
Same journal

Determination of <sup>137</sup>Ba nuclear quadrupole interactions in solids: a comparison of high field and zero field approaches.

Solid state nuclear magnetic resonance·2026
Same journal

Probing interlayer bromide in solvent intercalation of layered yttrium hydroxide via <sup>79/81</sup>Br SSNMR spectroscopy.

Solid state nuclear magnetic resonance·2026
Same journal

Single crystal sapphire spacers for in situ angle sensing and rotor stability diagnostics in MAS NMR.

Solid state nuclear magnetic resonance·2026
Same journal

Insights into the local adsorption of CO<sub>2</sub> in UiO-66.

Solid state nuclear magnetic resonance·2026
Same journal

<sup>75</sup>As NQR characterisation of cobaltite (CoAsS).

Solid state nuclear magnetic resonance·2026
See all related articles

Spatially resolved solid-state magic angle spinning (MAS) NMR of carbon-13 (13C) is detailed, featuring a novel device for enhanced spatial information and suppression of spinning sidebands.

Area of Science:

  • Solid-state Nuclear Magnetic Resonance (NMR) Spectroscopy
  • Materials Science
  • Chemical Physics

Background:

  • Solid-state MAS NMR is crucial for characterizing materials at the atomic level.
  • Obtaining spatially resolved information in solid-state NMR remains a challenge.
  • Existing methods often struggle with sensitivity and suppression of artifacts like spinning sidebands.

Purpose of the Study:

  • To provide a comprehensive account of spatially resolved solid-state MAS NMR of carbon-13 (13C).
  • To introduce and evaluate a novel device for generating synchronous field gradients.
  • To investigate factors affecting spatial resolution and data reduction strategies.

Main Methods:

  • Development of a device with field gradients rotating synchronously with the magic angle spinner.

Related Experiment Videos

  • Comparison of phase and frequency encoding techniques for spatial information acquisition.
  • Demonstration of spinning sideband suppression.
  • Application of 2D solid-state spectroscopy with spatial resolution on a rotor-synchronized MAS experiment.

    • Main Results:

    • Successful implementation of a device enabling spatially resolved solid-state 13C MAS NMR.
    • Demonstrated suppression of spinning sidebands for both phase and frequency encoding.
    • Spatial resolution and sensitivity were compared between different encoding methods.
    • Mapping of chemical structure using prior material knowledge for data reduction.
    • Revealed molecular order as a function of space in a 2D experiment.

    Conclusions:

    • The developed device and methods significantly advance spatially resolved solid-state NMR capabilities.
    • The study provides a framework for mapping chemical structure and molecular order with spatial resolution.
    • Indirect detection via 13C NMR offers insights into molecular mobility from proton wideline spectra.