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Related Concept Videos

IR Spectrum Peak Broadening: Hydrogen Bonding01:23

IR Spectrum Peak Broadening: Hydrogen Bonding

The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker bonds vibrate at lower frequencies. The stretching vibration of the strong O–H bond in alcohols and phenols (very dilute solution or gas phase) appears as a sharp peak at 3600–3650 cm−1.
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular hydrogen bonding...
High-Resolution Mass Spectrometry (HRMS)01:15

High-Resolution Mass Spectrometry (HRMS)

The resolution of a mass spectrometer depends on the efficiency of separating ions with different ion masses. The mass of an atom is approximated to the sum of the masses of protons and neutrons inside, considering the masses of protons and neutrons as equal. However, the masses of the proton (1.6726 × 10−24 g) and neutron (1.6749 × 10−24 g) are not truly equal. There is a minor error in the expression of atomic masses relative to the simplest atom of hydrogen. For example, the mass of helium...
Detection of Black Holes01:10

Detection of Black Holes

Although black holes were theoretically postulated in the 1920s, they remained outside the domain of observational astronomy until the 1970s.
Their closest cousins are neutron stars, which are composed almost entirely of neutrons packed against each other, making them extremely dense. A neutron star has the same mass as the Sun but its diameter is only a few kilometers. Therefore, the escape velocity from their surface is close to the speed of light.
Not until the 1960s, when the first neutron...
Inductively Coupled Plasma-Mass Spectrometry (ICP-MS): Interferences01:20

Inductively Coupled Plasma-Mass Spectrometry (ICP-MS): Interferences

Inductively coupled plasma–mass spectrometry (ICP–MS) is a highly selective and sensitive technique for accurate elemental analysis. Though the analysis of ICP–MS mass spectra is comparatively straightforward, it is affected by spectroscopic and non-spectroscopic interferences. Spectroscopic interferences arise when the plasma contains ionic species with an m/z value the same as the analyte ion. Spectroscopic interference can be categorized as isobaric, polyatomic ions, and refractory oxide ion...
Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...

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Related Experiment Video

Updated: Jul 20, 2026

Iridium(III) Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II
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Detection of H3+ in interstellar space

T R Geballe1, T Oka

  • 1Joint Astronomy Centre, University Park, Hilo, Hawaii 96720, USA. tom@jach.hawaii.edu

Nature
|November 28, 1996
PubMed
Summary

The detection of the trihydrogen cation (H3+) in interstellar molecular clouds is reported, confirming its role in initiating complex interstellar chemistry. This finding is crucial for understanding the chemical evolution of the universe.

Area of Science:

  • Astrochemistry
  • Interstellar Medium
  • Molecular Clouds

Background:

  • The trihydrogen cation (H3+) is theorized to be a key initiator of interstellar chemical reactions.
  • Previous attempts to detect H3+ in interstellar space have been unsuccessful.
  • The infrared spectrum of H3+ was measured in the laboratory in 1980.

Purpose of the Study:

  • To report the first successful detection of H3+ in interstellar molecular clouds.
  • To confirm the presence and significance of H3+ in driving interstellar chemistry.

Main Methods:

  • Absorption spectroscopy
  • Analysis of spectra from two molecular clouds.

Main Results:

  • Detection of H3+ absorption in the spectra of two molecular clouds.

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  • Evidence suggests H3+ is present in sufficient quantities to drive significant interstellar chemistry.
  • Accurate abundance determination is not yet possible.
  • Conclusions:

    • The detection of H3+ validates its proposed role in interstellar chemistry.
    • Further measurements will allow for better quantification of H3+'s impact on molecular cloud chemical evolution.
    • Ion-neutral reactions are critical for understanding chemical evolution in molecular clouds.