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Infrared Laser Spectroscopy of Jet-Cooled C2F6 near 10 μm
1Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom
Journal of Molecular Spectroscopy
|December 1, 1996
Abstract:
The nu5 (A2u) and nu7 (Eu) C-F stretching fundamentals of hexafluoroethane, C2F6, have been recorded in a supersonic jet by diode laser absorption spectroscopy. The parallel 5(1)o band is accompanied by five satellite bands, of which three have been assigned to hot bands. A fourth satellite band arises from 12CF313CF3. Transitions satisfying 0 /= 8. The band origins are 1117.10736 (7) cm-1 (5(1)o) and 1252.96950 (17) cm-1 (7(1)o, 0