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Distance between phosphine-sulfide sidechains of a disubstituted peptide by DRAMA 31P NMR

C A Klug1, D R Studelska, G Chen

  • 1Department of Chemistry, Washington University, St. Louis, MO 63130, USA.

Solid State Nuclear Magnetic Resonance
|December 1, 1996
PubMed
Summary

Dipolar Restoration at the Magic Angle (DRAMA) measured a 7.4 Å distance between phosphorus atoms in a helical peptide. Matrix isolation reduced linewidth, indicating less heterogeneity in the peptide

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