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Updated: Aug 9, 2026

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Preparation of Authigenic Pyrite from Methane-bearing Sediments for In Situ Sulfur Isotope Analysis Using SIMS
Published on: August 31, 2017
Polarized dispersion of X-rays in pyrite
1Department of Chemistry, University of California, Berkeley 94720, USA.
Abstract:
Diffraction of synchrotron radiation in a crystal of FeS2 reveals dipolar anisotropy of anomalous scattering by Fe near its K-absorption edge, in spite of the almost-regular octahedral geometry of the nearest S neighbors. At 7121 eV, the magnitude of f changes with polarization direction by as much as 0.7 electron units. No effects of quadrupolar anisotropy were detected.
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