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Identification of the absolute configuration of pectenotoxin-6, a polyether macrolide compound, by NMR spectroscopic
K Sasaki1, M Satake, T Yasumoto
1Faculty of Agriculture, Tohoku University, Sendai, Japan.
Bioscience, Biotechnology, and Biochemistry
|November 15, 1997
Abstract:
The absolute configuration of pectenotoxin-6 (4, PTX6), found in association with diarrhetic shellfish poisoning, was identified by NMR spectroscopy using a chiral anisotropic reagent, phenylglycine methyl ester (PGME), which was condensed with a carboxyl group of 4.