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Further characterization and kinetic parameter determination of a milk-clotting protease from Mucor bacilliformis

G D Venera1, C Machalinski, H Zumárraga

  • 1Instituto de Química y Fisicoquímica Biológicas (UBA-CONICET), Facultad de Farmacía y Bioquímíca, Buenos Aires, Argentina.

Insights

This study characterizes a Mucor bacilliformis aspartyl protease, revealing properties suitable for cheese production. The findings suggest this microbial protease could replace traditional bovine chymosin in dairy applications.

Area of Science:

  • Biochemistry
  • Enzymology
  • Food Science

Background:

  • Aspartyl proteases are crucial enzymes in food processing, particularly in cheese manufacture.
  • Bovine chymosin is the standard enzyme for milk clotting, but alternatives are sought for economic and ethical reasons.

Purpose of the Study:

  • To further characterize the milk-clotting aspartyl protease from Mucor bacilliformis.
  • To evaluate its biochemical and kinetic properties for potential use in cheese production.

Main Methods:

  • Determination of extinction coefficient, molecular mass, and isoelectric point (pI).
  • Evaluation of proteolytic activity and kinetic parameters using a specific hexapeptide substrate.
  • Assessment of the enzyme's stability and activity under varying pH and temperature conditions.

Main Results:

  • The Mucor bacilliformis protease exhibited an extinction coefficient of 1.61 mL/mg/cm, a molecular mass of 35,400 Da, and a pI of 5.2.
  • Proteolytic activity and kinetic parameters were successfully evaluated.
  • The enzyme's heat stability and optimal conditions for peptide cleavage were determined, indicating suitability for industrial applications.

Conclusions:

  • The characterized aspartyl protease from Mucor bacilliformis possesses properties favorable for milk-clotting activity.
  • This microbial protease shows potential as a viable and effective substitute for bovine chymosin in the cheese-making industry.

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