A Study on the Chemical Heterogeneity of Active Surface of Solid Catalysts
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Updated: Oct 30, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
Published on: January 17, 2020
1Department of Chemical Engineering, Jiangsu Institute of Petro-Chemical Technology, Changzhou, 213016, People's Republic of China
Abstract:
A method that can be used to characterize the chemical heterogeneity of active surface of solid catalyst is given. The chemical adsorption behavior of three adsorbates on Ni-W/F-Al2O3-SiO2 catalyst and supported Ni catalyst has been investigated. On the basis of fractal geometry, the roughness fractal dimension (Dr) and the chemisorption fractal dimension (Dc) of two kinds of catalyst are estimated. We use the difference between Dc and Dr to characterize the chemical heterogeneity of active sites on the catalytic surface. As a result, the chemical heterogeneity of the acid sites of Ni-W/F-Al2O3-SiO2 catalyst is very great. As for supported Ni catalyst, the chemical heterogeneity of active sites decreased when impregnating operation times in preparation of the catalyst increased. After impregnated four times, the chemical heterogeneity of its active surface of supported Ni catalyst is eliminated. Copyright 1997 Academic Press. Copyright 1997Academic Press
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