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Related Concept Videos

Photoluminescence: Applications01:14

Photoluminescence: Applications

Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...

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Low-energy Cathodoluminescence for (Oxy)Nitride Phosphors
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A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods

Danielson1, Devenney, Giaquinta

  • 1Symyx Technologies, 3100 Central Expressway, Santa Clara, CA 95051, USA. The authors all contributed equally to this work.

Science (New York, N.Y.)
|February 18, 1998
PubMed
Summary

Researchers discovered a novel luminescent inorganic oxide, strontium cerate (Sr2CeO4), through high-throughput screening. This material exhibits blue-white light emission, originating from a unique charge transfer process within its crystal structure.

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Phase-Dependent Control of Trap Depth and Persistent Luminescence in Strontium Aluminate Phosphors
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Phase-Dependent Control of Trap Depth and Persistent Luminescence in Strontium Aluminate Phosphors

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Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Solid-State Physics

Background:

  • Combinatorial material screening accelerates the discovery of novel compounds.
  • Luminescent inorganic oxides are crucial for various optoelectronic applications.
  • Understanding structure-property relationships is key to designing advanced materials.

Purpose of the Study:

  • To identify new luminescent inorganic oxides using automated synthesis and screening.
  • To characterize the structural, optical, and electronic properties of Sr2CeO4.
  • To elucidate the mechanism behind the observed luminescence.

Main Methods:

  • Automated thin-film synthesis for combinatorial library creation (>25,000 members).
  • Powder X-ray diffraction for crystal structure determination.
  • Optical spectroscopy (emission spectra, quantum yield, excited-state lifetime measurements).
  • Electron spin resonance and magnetic susceptibility measurements.

Main Results:

  • Discovery and identification of a novel luminescent inorganic oxide, Sr2CeO4.
  • Structural analysis revealed 1D chains of edge-sharing CeO6 octahedra isolated by Sr2+ cations.
  • Observed blue-white emission with a maximum at 485 nm and a quantum yield of 0.48 ± 0.02.
  • Evidence suggests luminescence arises from a ligand-to-metal Ce4+ charge transfer.

Conclusions:

  • Sr2CeO4 is a promising new material for luminescence applications.
  • The unique 1D chain structure influences its optical properties.
  • Ligand-to-metal charge transfer is the primary luminescence mechanism in Sr2CeO4.