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Analysis of the K-Subband Structure of the nu1 Fundamental of Propargyl Radical H2CC identical withCH
1Chemistry Department and Rice Quantum Institute, Rice University, Houston, Texas, 77005
Journal of Molecular Spectroscopy
|February 25, 1998
Abstract:
The K-subband structure of the acetylenic CH stretch fundamental, nu1, of propargyl radical, CH2CCH, has been assigned and analyzed. The K = 0, 1-, 1+, 3, 4, 5, and 6 upper state energies totaling 109 levels could be accurately fitted with Watson's fourth-order A-reduced Hamiltonian. The K = 2 subband was perturbed with the level crossing between N = 17 and 18. Copyright 1998 Academic Press. Copyright 1998Academic Press