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Split-and-pool Synthesis and Characterization of Peptide Tertiary Amide Library
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Synthesis and conformational analysis of two 2-oxopiperazine-containing tetrapeptide analogues

A Pohlmann1, D Guillaume, J C Quirion

  • 1Laboratoire de Chimie Thérapeutique, Faculté des Sciences Pharmaceutiques et Biologiques, Paris, France.

The Journal of Peptide Research : Official Journal of the American Peptide Society
|March 27, 1998
PubMed

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Structure of Amines01:19

Structure of Amines

The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’ carbon–carbon bond (154 pm). These aspects are illustrated in Figure...