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Related Experiment Videos

Primary extinction in cylinders and spheres

Thorkildsen1, Larsen

  • 1Department of Mathematics and Natural Science, Stavanger College, Ullandhaug, Norway. gunnar.thorkildsen@tn.his.no

Acta Crystallographica. Section A, Foundations of Crystallography
|April 2, 1998
PubMed
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Nonsymmetrical X-ray diffraction in a perfect rectangular t x l crystal. Extinction and absorption.

Acta crystallographica. Section A, Foundations of crystallography·2000

Researchers derived analytical expressions for primary extinction factors in perfect crystals. This advancement in X-ray diffraction analysis provides the first five terms of a series expansion for accurate scattering angle calculations.

Area of Science:

  • Solid State Physics
  • Crystallography
  • X-ray Diffraction

Background:

  • The primary extinction factor is crucial for understanding X-ray diffraction in perfect crystals.
  • Analytical solutions for this factor are complex and often limited in scope.
  • Previous methods struggled to provide comprehensive expressions across all scattering angles.

Purpose of the Study:

  • To derive analytical expressions for the primary extinction factor in perfect crystals.
  • To develop a series expansion for the primary extinction factor.
  • To cover the entire range of scattering angles (theta oh).

Main Methods:

  • Transformation of Takagi equations into angular coordinates.
  • Establishment of recurrence relations for Bragg and Laue boundary-value Green functions.

Related Experiment Videos

  • Integration over entrance and exit surfaces of the crystal.
  • Main Results:

    • Obtained analytical expressions for the primary extinction factor coefficients.
    • Successfully derived the first five terms of the series expansion.
    • Calculations cover the full range of scattering angles.

    Conclusions:

    • The developed method provides a robust framework for calculating primary extinction factors.
    • This approach offers improved accuracy in X-ray diffraction analysis of perfect crystals.
    • The use of symbolic computation software (Mathematica, Maple) facilitates complex calculations.